It depends on who's going to see it, and the exact nature of the job you're going for, but the cases where it will be beneficial are limited.
If you know for certain that the hiring manager themselves will see the document, and you have reason to believe that this will impress them, then go ahead - but be wary that impressing them with your graphic design skills is only relevant If there is any graphic design skill required for the job.
Otherwise, it's superfluous information that makes it look like you're trying too hard, and you should go with a more standard, more easily reproduced, more editable format.
And, for you personally, it will be less expensive to print copies.